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The nature of plasmon-exciton co-driven surface catalytic reaction

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1 The nature of plasmon-exciton co-driven surface catalytic reaction
专业:凝聚态物理 导师:王培杰 报告人:刘文 时间:

2 目录 研究背景 实验准备 实验过程 SERS of PNA CONTENTS G-SERS of PNA 实验结论 01 2-1 02
2-2 SERS of PNA 目录 2-3 G-SERS of PNA CONTENTS 03 实验结论

3 The First Part 研究背景 We are pursuing the best!

4 研究背景 We are pursuing the best!

5 研究背景 We are pursuing the best!

6 The Second Part 实验过程 We are pursuing the best!

7 实验过程-实验准备-实验装置 We are pursuing the best!

8 实验过程-实验准备-分子选择 We are pursuing the best!

9 实验过程-实验准备-基底表征 We are pursuing the best!

10 等离子体共振峰峰位大约在560nm处,相比785nm的激光波长,更接近于532nm。
实验过程-实验准备-基底表征 We are pursuing the best! 粗糙银电极光吸收反射模式光谱图: 粗糙后的银电极表面粒径均 匀,粗糙度较好,局域表面 等离子体共振峰峰位大约在560nm处,相比785nm的激光波长,更接近于532nm。

11 实验过程-SERS of PNA We are pursuing the best!

12 实验过程-SERS of PNA We are pursuing the best!

13 实验过程-SERS of PNA We are pursuing the best!

14 实验过程-G-SERS of PNA We are pursuing the best!

15 实验过程-G-SERS of PNA We are pursuing the best!

16 实验过程-G-SERS of PNA We are pursuing the best!

17 实验过程-G-SERS of PNA We are pursuing the best! PH=12 PH=3

18 实验过程-G-SERS of PNA We are pursuing the best! 785nm

19 实验过程-SERS/G-SERS of PNA
532nm 785nm

20 The Third Part 结论 We are pursuing the best!

21 02 01 结论 We are pursuing the best!
The mechanism of plasmon-exciton co-driven chemical reaction in electrochemical SERS is revealed, where the incident laser is 785 nm. In the graphene-Ag hybrid system, the Fermi level of hybrid system can be increased eV, due to the existence of graphene. Hence, the G-SERS has more advantages and high efficiency than SERS in the field of surface catalytic reactions. The plasmon–exciton co-driven surface catalytic reactions in electrochemical G-SERS were reported, which demonstrate great advantages for plasmon–exciton co-driven chemical reactions on G-SERS in liquid environments, and which can be potentially applied in the surface spectral analysis in electrochemical environments.

22 C 谢谢观看与聆听 专业:凝聚态物理 导师:王培杰 报告人:刘文 时间:


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